Study of structural and electrochemical characteristics of Co-based hypo–hyper d-electrocatalysts for hydrogen evolution

P. Paunovic, O. Popovski, A. Dimitrov, D. Slavkov, E. Lefterova, S. Hadzi Jordanov

doi:10.1016/j.electacta.2007.01.053

Study of structural and electrochemical characteristics of Co-based hypo–hyper d-electrocatalysts for hydrogen evolution

Journal

Electrochimica Acta

Date Issued

2007-04

Author(s)

P. Paunovic, O. Popovski, A. Dimitrov, D. Slavkov, E. Lefterova, S. Hadzi Jordanov

DOI

10.1016/j.electacta.2007.01.053

Abstract

Structural and electrochemical characteristics of hypo–hyper d-electrocatalytic materials aimed for preparation of electrodes for hydrogen evolution were studied. The basic catalytic material was prepared of 10% amorphous Co (grain size <2 nm), 18% amorphous TiO2 and Vulcan XC-72, by sol–gel procedure. A number of modifications were applied aimed at improving the materials performances: (i) TiO2 was transformed into anatase by heating at 480 ◦C for 1 h, (ii) multiwalled carbon nanotubes (MWCNT) were used as a catalyst support instead of Vulcan XC-72 and (iii) Mo was added to Co phase in a quantity of 25 at.% (Mo:Co = 1:3). Both, material’s intrinsic catalytic activity and surface area were affected by these modifications. As a result, the electrocatalytic activity for hydrogen evolution was improved, e.g. transformation of TiO2 into anatase form lowers the HER overpotential (η) for 15mV at 60mAcm−2. Introduction of MWCNTs lowered η for 30mV, while addition of Mo to metallic phase for 40mV. The complete modification of all three catalyst’s components (10% MoCo3 + 18% anatase + MWCNTs) was the most effective with 60mV
decrease of overpotential. Characterization was made by XRD, SEM, IR and XPS methods. Surface area was measured by means of cyclic voltammetry.

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