Faculty of Technology and Metallurgy

Permanent URI for this communityhttps://repository.ukim.mk/handle/20.500.12188/20

Browse

Search Results

Now showing 1 - 10 of 309
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Matrix and graph-theoretical modeling of quality function deployment in the textile industry
    (University of Belgrade, 2026)
    Stevkovska-Stojanovska, Ruzica
    ;
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Reflectivity from electrochemically protected Nb surfaces
    (Engineering Society of Corrosion, 2015-06-15)
    Corrosion resistance of fine mechanically polished and electro-polished Nb surfaces were tested by elliposmetric measurements the reflectivity at various angle of incidence. The same measurements were also repeated on electro-polished Nb surface anodic ally oxidized in 1M H2SO4 during 30 s in the potential/voltage range from 0 to 100 V. From the minimum value of measured reflectivity parallel to plane of incidence, the Brewster angle for each investigated sample was determined. The simultaneous measurements of corrosion parameters Brewster angle have shown that the values of Brewster's angle should be used for fast testing the quality of protected metal surfaces.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Photoelectrochemical Study of Anodically Formed Oxide Films on Niobium Surfaces
    (CROATIAN CHEMICAL SOC, 2010-07)
    The semi-conducting properties of electrochemically formed oxide films onto Nb surface in 1 M H(2)SO(4) have been studied by photo-electrochemical measurements. By cyclic voltammetry the I vs. E profile of active/passive transition of Nb electrode has been recorded in the potential region from -0.5 to 8 V (SCE). The photocurrent maximums, band gap energies and flat potentials of anodic oxide films formed by stepwise rising of anodic voltage from 10 to 100 V on Nb electrode have been determined. Using Raman spectroscopy the development of crystalline structure in the films with different resultant thickness has been analysed. The semi-conducting properties of niobium oxides with development of crystalline structure have been discussed in term of breakdown processes in the films. The thresholds of transition from amorphous to crystalline form of anodic oxide films depending of applied voltages and time of polarization have been determined.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    TOWARDS SUSTAINABLE EXTRACTION OF OIL FROM APRICOT KERNELS
    (2026-02-12)
    Amiti, Belinda
    ;
    ;
    Deep eutectic solvents (DES) are gaining attention as green alternatives to conventional volatile organic solvents for the extraction of natural products. Their ease of preparation from inexpensive, biodegradable components, along with low toxicity and tunable physicochemical properties, makes them promising candidates for designing eco-efficient extraction processes. In this work, four DES systems based on choline chloride (ChCl) as hydrogen bond acceptor and different hydrogen bond donors glycerol, lactic acid, acetic acid, and glucose were synthesized and evaluated as co-solvents with n-hexane for the ultrasonic-assisted extraction of oil from apricot kernels. The DESs were characterized in terms of pH, density (δ), viscosity (μ), and electrical conductivity (σ) to better understand how their physical properties influence extraction performance. Oil extraction experiments demonstrated that the DES composition and its physical properties have a marked impact on extraction efficiency. Under optimized ultrasonic conditions, the use of ChCl:AA (1:2) as a co-solvent with n-hexane yielded the highest oil recovery of 26.62%, surpassing pure n-hexane, which afforded only 24.10% under the same conditions. In contrast, ChCl:GLY (1:2), ChCl:LA (1:2), and ChCl:GLU (2:1) resulted in lower oil yields of 18.95%, 22.23%, and 13.26%, respectively. The superior performance of ChCl:AA is attributed to its combination of relatively low viscosity, and high conductivity, which collectively promote enhanced mass transfer, more efficient cell disruption, and improved solubilization of lipophilic components when assisted by ultrasonic cavitation. Overall, this study highlights the importance of tailoring the physicochemical properties of DES to maximize performance and demonstrates the potential of DES n-hexane systems as green, efficient, and scalable alternatives to conventional solvent based processes for the valorization of apricot kernel oil and other plant derived lipids.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Optimization of Oil Extraction Process from White Mustard Seeds Using Response Surface Methodology
    (National and University Library of the Republic of Srpska, 2024-02-21)
    Stojchevski, Martin
    ;
    Slaveski, Angelina
    ;
    ;
    ;
    In this study, response surface methodology (RSM) was used for the determination of the effect of two process parameters (extraction temperature and extraction time) and their interaction on the yield of the total extract from white mustard seeds (Sinapis alba l.), as well as the creation of a mathematical model, 3D response surface, and the establishment of an optimal extraction region. Ethanol 96% as a green solvent was employed to separate biological compounds from white mustard (Sinapis alba l.) seeds by applying ultrasound-assisted extraction (UAE). UAE was performed at the temperature of 25, 30, and 35℃ for a duration of 30, 60, and 90 min. UAE as a modern extraction technique showed great performance, while the ethanol solvent provided a high yield of compounds. The utilized RSM design adequately fit the experimental data with a high coefficient of determination (R2= 0.9365) and low mean absolute error (MAE= 1.12242). Estimated effects for the yield of the total extract showed that the extraction time, the temperature, and the interaction between time and temperature influenced positively, while the time-squared and the temperature-squared influenced negativity on the yield of the total extract. Analysis of variance showed that 2 effects have P-values less than 0.05. The optimal yield of the total extracted oil was 15.19% at the temperature of 35℃ for a duration of 70.3 min.
  • Some of the metrics are blocked by your 
    Item type:Publication,
  • Some of the metrics are blocked by your 
    Item type:Publication,
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Electrochemical behavior of tantalum in potassium hydroxide solutions
    (International Association of Physical Chemists (IAPC), 2018-08-31)
    The electrochemical behavior of tantalum in various concentrations of KOH solutions (0.1 M -10 M), was investigated using the evolution of the open circuit potentialin time, cyclic voltammetry and ellipsometricmeasurements. Depending on KOH concentrations, the open circuit potential measurements have shown three distinct behaviors concerning oxide film formation on the electrode surface and its dissolution. The cyclic voltammetry measurements were performed in various potential ranges, from -1.4 to 8 V, different concentrations of KOH solutions (0.110 M) and sweep rates ranging from 0.005 V/s to 1 V/s. In the passive region, very stable passive films were formed, which reduction has not been possible during cathodic polarization even at highly concentrated KOH solutions. In the trans-passive region, the very strong peak at 1.65 V was monitored, which nature and chemical composition is still not well known.
  • Some of the metrics are blocked by your 
    Item type:Publication,
    Preformulation Characterization of Hydroxypropyl Cellulose Microparticles for Drug Delivery Applications:A Basis for Rational Design and Process Optimization
    (HDKI, 2025)
    Georgievska, Tamara
    ;
    Trajkovic, Stefan
    ;
    Stojanov, Darko
    ;
    Pecova, Monika Stojanovska
    ;